lst = [{'python':[1, 2], 'c++':[3, 4, 5]},
{'c':[6], 'php':[7, 8, 9 , 0], 'java':[13, 14]}]
lst_dic = [(key,) + tuple(val) for dic in lst for key, val in dic.items()]
print (lst_dic)
'''
run:
[('python', 1, 2), ('c++', 3, 4, 5), ('c', 6), ('php', 7, 8, 9, 0), ('java', 13, 14)]
'''